热带地理 ›› 2019, Vol. 39 ›› Issue (3): 337-346.doi: 10.13284/j.cnki.rddl.003141
王伟权1,2,张瑞杰2,余克服2,王英辉2,潘长桂2,曾维斌1,2
收稿日期:
2019-02-22
修回日期:
2019-04-10
出版日期:
2019-05-05
发布日期:
2019-05-05
通讯作者:
余克服(1969—),男,湖北公安人,教授,博士,主要从事珊瑚礁地质,生态与环境的研究,(E-mail)kefuyu@scsio.ac.cn。
作者简介:
王伟权(1991—),男,广西南宁人,硕士研究生,主要研究方向为海洋环境污染,(E-mail)247943518@qq.com;
基金资助:
国家自然科学基金(91428203);广西科技项目(AD17129063);广西八桂学者项目(2014BGXZGX03)
Wang Weiquan1,2, Zhang Ruijie2, Yu Kefu2, Wang Yinghui2, Pan Changgui2 and Zeng Weibin1,2
Received:
2019-02-22
Revised:
2019-04-10
Online:
2019-05-05
Published:
2019-05-05
摘要:
以16种优控多环芳烃(PAHs)为研究对象,分别于2017年夏季(8月)和冬季(12月)采集广西廉州湾和三娘湾的河口和海岸带14个站位的表层海水样品,利用固相萃取、气相色谱-质谱联用仪对其进行分析,探讨其时空分布、组成和来源,并评价其生态风险。结果表明:廉州湾和三娘湾河口及海岸带水体中多环芳烃单体的平均质量浓度总体上与其溶解度和极性呈正相关关系,即以2~3环芳烃为主,4~6环芳烃检出率和质量浓度均较低。PAHs总质量浓度(∑16PAHs)在夏季河口水体(72.71 ng/L)明显高于海岸带水体(56.28 ng/L)(t检验,p<0.01),冬季河口(106.67 ng/L)与海岸带(92.43 ng/L)差异不显著(t检验,p>0.05)。冬季河口和海岸带PAHs质量浓度均明显高于夏季。大风江和南流江PAHs的入海通量达525.3 kg/a,夏秋季占85%以上,反映了雨季河流对海岸带具有明显的影响。南流江PAHs入海通量占2条河流总量的87%以上,对廉州湾和三娘湾的影响最大。运用同分异构体比值和主成分分析方法对海水中PAHs进行来源解析,结果表明:夏季主要为燃烧源和石油源的混合来源,冬季主要为燃烧源。与其他国家或地区相比,廉州湾和三娘湾海水中PAHs质量浓度处于较低水平。生态风险评价结果显示廉州湾和三娘湾表层海水中的PAH风险较小。
王伟权,张瑞杰,余克服,王英辉,潘长桂,曾维斌. 广西廉州湾和三娘湾表层水体中多环芳烃的时空分布与来源解析[J]. 热带地理, 2019, 39(3): 337-346.
Wang Weiquan, Zhang Ruijie, Yu Kefu, Wang Yinghui, Pan Changgui and Zeng Weibin. Occurrence, Distribution and Source Analysis of Polycyclic Aromatic Hydrocarbons (PAHs) in the Surface Waters of the Lianzhou Bay and Sanniang Bay, Guangxi[J]. TROPICAL GEOGRAPHY, 2019, 39(3): 337-346.
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