热带地理 ›› 2020, Vol. 40 ›› Issue (2): 335-345.doi: 10.13284/j.cnki.rddl.003214
王家录1,2, 任娟1, 王勇1(), 李维杰1, 娄昭2, 陈佳3
收稿日期:
2019-10-18
修回日期:
2019-12-12
出版日期:
2020-03-10
发布日期:
2020-05-15
通讯作者:
王勇
E-mail:190966549@qq.com
作者简介:
王家录(1969—),男,贵州织金人,副教授,博士生,主要研究方向为岩溶环境与全球变化,(E-mail) lu226@163.com。
基金资助:
Wang Jialu1,2, Ren Juan1, Wang Yong1(), Li Weijie1, Lou Zhao2, Chen Jia3
Received:
2019-10-18
Revised:
2019-12-12
Online:
2020-03-10
Published:
2020-05-15
Contact:
Wang Yong
E-mail:190966549@qq.com
摘要:
为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明:1)多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO2等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2)利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3)δ 18O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程(主要是呼吸作用过程);而对比水库水体和大气降水的d-excess(d值)发现,水库水体的d值(8.21‰)显著偏低于当地大气降水的d值(9.64‰),说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。
中图分类号:
王家录, 任娟, 王勇, 李维杰, 娄昭, 陈佳. 贵州夜郎湖表层水体地球化学昼夜变化及其影响因素[J]. 热带地理, 2020, 40(2): 335-345.
Wang Jialu, Ren Juan, Wang Yong, Li Weijie, Lou Zhao, Chen Jia. Diel Variations of Hydrochemistry and Influencing Factors in the Surface Water of the Yelanghu Reservoir in Puding, Guizhou Province[J]. Tropical Geography, 2020, 40(2): 335-345.
表4
夜郎湖水库理化指标PCA结果"
指标 | PC1 | PC2 | PC3 | PC4 | PC5 | PC6 |
---|---|---|---|---|---|---|
SpC | -0.441 | 0.632 | -0.068 | 0.251 | -0.318 | 0.178 |
DO | 0.158 | 0.641 | -0.04 | 0.283 | -0.278 | 0.433 |
pH值 | 0.954 | 0.067 | -0.074 | 0.119 | -0.043 | 0.046 |
水温 | 0.782 | -0.042 | 0.061 | -0.29 | 0.056 | 0.316 |
K+ | -0.159 | -0.302 | -0.305 | 0.729 | 0.116 | 0.027 |
Na+ | 0.4 | -0.463 | -0.163 | 0.344 | 0.035 | -0.096 |
Ca2+ | 0.204 | 0.296 | -0.031 | 0.008 | 0.822 | 0.005 |
Mg2+ | -0.229 | 0.218 | -0.406 | 0.267 | 0.529 | 0.432 |
Cl- | 0.03 | 0.53 | 0.679 | 0.242 | -0.056 | 0.198 |
0.026 | 0.217 | 0.886 | 0.164 | 0.183 | 0.059 | |
-0.197 | -0.25 | 0.630 | 0.028 | 0.415 | -0.146 | |
-0.088 | 0.702 | -0.386 | -0.12 | 0.155 | -0.405 | |
SIc | 0.738 | 0.505 | -0.309 | 0.021 | 0.131 | -0.152 |
气温 | 0.469 | 0.452 | 0.208 | -0.029 | -0.115 | -0.525 |
pCO2 | -0.793 | 0.401 | -0.126 | -0.19 | 0.11 | -0.224 |
水位 | -0.066 | 0.048 | -0.077 | -0.731 | 0.081 | 0.464 |
方差贡献率/% | 21.66 | 17.28 | 14.08 | 10.22 | 8.97 | 8.19 |
累计方差贡献率/% | 21.66 | 38.93 | 53.01 | 63.24 | 72.21 | 80.40 |
[1] | 陈贞龙 . 2010. 黔西滇东地区煤层气富集规律及流体作用研究. 北京: 中国地质大学(北京). |
[ Chen Zhenlong . 2010. Study on the Law of Coalbed Gas Enrichment and Fluid Action in the Eastern Yunnan-Western Guizhou Area. Beijing: China University of Geosciences (Beijing). ] | |
[2] | Clark I D and Fritz P . 1997. Environmental Isotopes in Hydrogeology. New York: CRC Press. |
[3] | Dansgard W . 1964. Stable Isotopes in Precipitation. Tellus, 16(4):436-468. |
[4] | Fritz P and Fontes J C . 1986. Handbook of Environmental Isotope Geochemistry. New York: Elsevier. |
[5] | Hayashi Masaki, Vogt Tobias, Mächler Lars and Schirmer Mario . 2012. Diurnal Fluctuations of Electrical Conductivity in a Pre-alpine River: Effects of Photosynthesis and Groundwater Exchange. Journal of Hydrology, 450:93-104. |
[6] | Jiang Y J, Hu Y J and Schirmer M . 2013. Biogeochemical Controls on Daily Cycling of Hydrochemistry and δ 13C of Dissolved Inorganic Carbon in a Karst Spring-Fed Pool. Journal of Hydrology , 478:157-168. |
[7] | Kroopnick P M . 1975. Respiration, Photosynthesis, and Oxygen Isotope Fractionation in Oceanic Surface Water. Limnology and Oceanography, 20(6):988-992. |
[8] | 李建鸿, 蒲俊兵, 袁道先, 刘文, 肖琼, 于奭, 张陶, 莫雪, 孙平安, 潘谋成 . 2015. 岩溶区地下水补给型水库表层无机碳时空变化特征及影响因素. 环境科学, 36(8):2833-2842. |
[ Li Jianhong, Pu Jjunbing, Yuan Daoxian, Liu Wen, Xiao Qiong, Yu Shi, Zhang Tao, Mo Xue, Sun Pingan and Pan Moucheng . 2015. Variations of Inorganic Carbon and its Impact Factors in Surface-Layer Waters in a Groundwater-Fed Reservoir in Karst Area, SW China. Environmental Science, 36(8):2833-2842. ] | |
[9] | 李强 . 2004. 水生藻类碳酸酐酶(CA)对碳酸钙沉积速率控制的试验研究. 广西:广西师范大学. |
[ Li Qiang . 2004. An Experimental Study on the Effect of Aquatic Algae Carbonic Anhydrase on Calcite Precipitation. Guangxi: Guangxi Normal University. ] | |
[10] | 李维杰, 王建力, 王家录 . 2018. 西南地区不同地形降水稳定同位素特征及其水汽来源. 长江流域资源与环境, 27(5):1132-1142. |
[ Li Weijie, Wang Jianli and Wang Jialu . 2018. Characteristics of the Stable isotopes in Precipitation and the Source of Water Vapor in Different Terrain in the Southewest Region. Resources and Environment in the Yangtze Basin, 27(5):1132-1142. ] | |
[11] | Li Zhenwei and Xu Xiangli . 2017. Annual Runoff is Highly Linked to Precipitation Extremes in Karst Catchments of Southwest China. Journal of Hydrometeorology, 18(10):2745-2759. |
[12] | 林秋奇, 韩博平 . 2001. 水库生态系统特征研究及其在水库水质管理中的应用. 生态学报, 26(6):1034-1040. |
[ Lin Qiuqi and Han Boping . 2001. Reservoir Limnology and Its Application in Water Quality Management an Overview. Acta Ecologica Sinica, 26(6):1034-1040. ] | |
[13] | 刘再华 . 2001. 碳酸酐酶对碳酸盐岩溶解的催化作用及其在大气CO2沉降中的意义. 地球学报, 22(5):477-480. |
[ Liu Zhaihua . 2001. The Role of Carbonic Anhydrase as an Activator in Carbonate Rock Dissolution and Its Significance in Atmospheric CO2 Precipitation. Acta Geoscientia Sinica, 22(5):477-480. ] | |
[14] | Liu Zaihua, Li Qiang, Sun Hailong and Wang Jinliang . 2007. Seasonal, Diurnal and Storm-scale Hydrochemical Variations of Typical Epikarst Springs in Subtropical Karst Areas of SW China: Soil CO2 and Dilution Effects. Journal of Hydrology, 337(1/2):207-223. |
[15] | 吕迎春, 刘丛强, 王仕禄, 徐刚, 刘芳 . 2007. 贵州喀斯特水库红枫湖、百花湖p(CO2)季节变化研究. 环境科学,( 12):2674-2681. |
[ Lyu Yingchun, Liu Congqiang, Wang Shiliu, Xu Gang and Liu Fang . 2007. Seasonal Variability of p( CO2) in the Two Karst Resrviors, Hongfeng and Baihua Lakes in Guizhou Province, China. Environmental Science, ( 12):2674-2681. ] | |
[16] | Mader Michael, Schmidt Christian, Van Geldern Robert and Barth Johannes A C . 2017. Dissolved Oxygen in Water and its Stable Isotope Effects: A Review. Chemical Geology, 473:10-21. |
[17] | 毛庆亚, 王建力, 王家录, 李文 . 2017. 贵州安顺与重庆北碚大气降水中δD和δ 18O特征分析 . 西南大学学报(自然科学版), 39(2):114-120. |
[ Mao Qingya, Wang Jianli, Wang Jialu and Li Wen . 2017. Analysis of the Characteristics of δD and δ 18O in the Meteoric Precipitation in Anshun, Guizhou Province and Chongqin Beibei. Journal of Southwest University (Natural Science Edition) , 39(2):114-120. ] | |
[18] | 莫雪, 蒲俊兵, 袁道先, 章程, 何师意, 于奭, 刘文, 张陶, 周建超, 杨会, 唐伟 . 2014. 亚热带典型岩溶区地表溪流溶解无机碳昼夜变化特征及其影响因素. 第四纪研究, 34(4):873-880. |
[ Mo Xue, Pu Junbing, Yuan Daoxian, Zhang Cheng, He Shiyi, Yu Shi, Liu Wen, Zhang Tao, Zhou Jianchao, Yang Hui and Tang Wei . 2014. Diurnal Variation of Dissolved Inorganic Carbon in Surface Streams in Typical Subtropical Karst Areas and its Influencing Factors. Quaternary Research, 34(4):873-880. ] | |
[19] | Nimick D A, Gammons C H and Parker S R . 2011. Diel Biogeochemical Processes and their Effect on the Aqueous Chemistry of Streams: A Review. Chemical Geology, 283(1/2):3-17. |
[20] |
Parker Stephen R, Poulson Simon R, Gammons Christopher H and DeGrandpre Michael D . 2005. Biogeochemical Controls on Diel Cycling of Stable Isotopes of Dissolved O2 and Dissolved inorganic Carbon in the Big Hole River, Montana. Environmental Science & Technology, 39(18):7134-7140.
doi: 10.1021/es0505595 pmid: 16201639 |
[21] |
Pu Junbing, Li Jianhong, Mitra B Khadka, Jonathan B Martin, Zhang Tao, Yu Shi and Yuan Daoxian . 2017. In-Stream Metabolism and Atmospheric Carbon Sequestration in a Groundwater-fed Karst Stream. Science of the Total Environment, 579:1343-1355.
doi: 10.1016/j.scitotenv.2016.11.132 pmid: 27913023 |
[22] |
Shen Tianming, Li Wei, Pan Weizhi, Lin Shengyan, Zhu Min and Yu Longjiang . 2017. Role of Bacterial Carbonic Anhydrase during CO2, Capture in the CO2-H2O-Carbonate System. Biochemical Engineering Journal, 123:66-74.
doi: 10.1016/j.bmc.2015.12.005 pmid: 26712095 |
[23] | 申献辰 . 1994. 天然水化学. 北京: 中国环境科学出版社. |
[ Shen Xianchen. 1994. Natural Water Chemistry. Beijing: China Environmental Science Press. ] | |
[24] | 沈照理, 朱宛华, 钟佐燊 . 1993. 水文地球化学基础. 北京: 地质出版社. |
[ Shen Zhaoli, Zhu Wanhua and Zhong Zuoshen . 1993. Basic Hydrogeochemistry. Beijing: Geology Press. ] | |
[25] | 唐黎, 李秋华, 陈椽, 王龙, 何应, 陈峰峰, 高永春, 骆兰 . 2017. 贵州普定水库沉积物重金属分布及污染特征. 中国环境科学, 37(12):4710-4721. |
[ Tang Li, Li Qiuhua, Chen Chuan, Wang Long, He Ying, Chen fengfeng, Gao Yongchun and Luo Lan . 2017. Distribution and Pollution Characteristics of Heavy Metals in Sediments of Puding Reservoir, Guizhou Province. Chinese Environmental Science, 37(12):4710-4721. ] | |
[26] | 王安华, 牟军, 黄道光, 石磊 . 2010. 贵州安顺旧州晚二叠世龙潭期沉积特征及地质意义. 贵州地质, 27(4):241-244. |
[ Wang Anhua, Mou Jun, Huang Daoguang and Shi Lei . 2010. Sedimentary Characteristics and Geological Significance of Longtan Period in Late Permian in Jiuzhou, Anshun, Guizhou. Guizhou Geology, 27(4):241-244. ] | |
[27] | 王奇岗, 肖琼, 赵海娟, 王建力, 郭永丽, 张清华 . 2019. 高分辨率监测下的漓江省里断面生物地球化学特征分析. 环境科学, 40(3):1-22. |
[ Wang Qigang, Xiao Qiong, Zhao Haijuan, Wang Jianli, Guo Yongli and Zhang Qinghua . 2019. Biongeochemical Characteristics in Shengli Site of Lijiang River under the High Resolution Monitoring. Environmental Science, 40(3):1-22. ] | |
[28] | 杨明德 . 1998. 喀斯特流域水文地貌系统. 北京: 地质出版社. |
[ Yang Mingde. 1998. Hydrogeomorphic System of Karst Watershed. Beijing: Geology Press. ] | |
[29] | 于正良, 杨平恒, 赵瑞一, 李林立, 张琳, 童小容, 罗刚 . 2015. 春季生物作用对山地岩溶池水地球化学特征的影响. 环境科学, 36(4):1263-1269. |
[ Yu Zengliang, Yang Pingheng, Zhao Ruiyi, Li Linli, Zhang Lin, Tong Xiaorong and Luo Gang . 2015. Influences of Biological Processes on Geochemical Characteristics: An Axample of a Mountain Karst Pool in Spring Season. Environmental Science, 36(4):1263-1269. ] | |
[30] | Yuan D X . 1997. Sensitivity of Karst Process to Environmental Change along the Pep ii Transect. Quaternary International, 37:105-113. |
[31] | 袁道先, 蒋勇军, 沈立成, 蒲俊兵, 肖琼 . 2016. 现代岩溶学. 北京: 科学出版社. |
[ Yuan Daoxian, Jiang Yongjun, Shen Licheng , Pu Junbing and Xiao Qiong. 2016. Modern Karst Science. Beijing: Science Press. ] | |
[32] | 张陶, 蒲俊兵, 袁道先, 章程, 何师意, 于奭, 刘文, 莫雪, 周建超, 杨会, 唐伟 . 2014. 亚热带典型岩溶区地表溪流水文地球化学昼夜变化及其影响因素研究. 环境科学, 35(8):2944-2951. |
[ Zhang Tao, Pu Junbing, Yuan Daoxian, Zhang Cheng, He Shiyi, Yu Shi, Liu Wen, Mo Xue, Zhou Jianchao, Yang Hui and Tang Wei . 2014. Diel Variations of Hydrochemistry and Influencing Factors in a Surface Stream in Subtropical Karst Area, SW China. Environmental Science, 35(8):2944-2951. ] | |
[33] | 张陶, 蒲俊兵, 袁道先, 李建鸿 . 2016. 广西官村岩溶溪流中生物地球化学控制的DIC和$NO^{-}_{3}$昼夜变化研究 . 地质学报, 90(8):1965-1977. |
[ Zhang Tao, Pu Junbing, Yuan Daoxian and LI Jianhong . 2016. Biogeochemical Controls on Daily Cycling of DIC and $NO^{-}_{3}$ of Guancun Karst Steam in Guanxi . Acta Geologica Sinica, 90(8):1965-1977. ] | |
[34] | Zhang Cheng, Wang Jinliang and Yan Jun . 2016. Diel Cycling and Flux of $HCO^{-}_{3}$ in a Typical Karst Spring-fed Stream of Southwestern China . Acta Carsologica, 45(2):107-122. |
[35] | 普定县人民政府. 2017. 气候与健康旅游. (2016-07-22)[2017-05-08]. . |
[ People’s Government of Puding County. 2017. (2016-07-22). [2017-05-08]. Climate and Health Tourism. ] | |
[36] | 赵宗权, 曹玉平, 焦树林, 袁热林, 邓飞艳, 张倩 . 2018. 龙滩水库表层水体CO2分压和水化学特征. 湿地科学, 16(6):793-800. |
[ Zhao Zongquan, Cao Yuping, Jiao Shulin, Yuan Relin, Deng Feiyan and Zhang Qian . 2018. Characteristics of CO2 Partial Pressure and Hydrochemistry in Surface Water of Longtan Reservoir. Wetland Science, 16(6):793-800. ] |
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