Two hills in a typical Karst hilly area in Jiulong, Yingde, were selected as the study area. To understand soil calcium element migration and enrichment in different geomorphic conditions in Karst area, the bareness rate of rock, soil thickness and vegetation at hill top, cliff, slope, dry gully, hill foot and water depression were surveyed, and different soil samples were collected. Atomic absorption spectrophotometer was used to measure the contents of total calcium, exchangeable calcium, and water soluble calcium. The results showed that the total calcium content of soil in water depression was 62.397 g/kg, the highest in all the geomorphic locations, next were hill top, slope, cliff, and gully successively. The highest contents of exchangeable calcium and water soluble calcium also occurred in the soil of water depression, which were, respectively, 4.582 and 0.223 g/kg. The contents of exchangeable calcium and water soluble calcium were not significantly different at hill top, slope, cliff, and gully, which were 1.560-2.421 g/kg and 0.057-0.180 g/kg respectively. The research indicated that soil carbonate content and pH value had significant positive correlations with total calcium, exchange calcium, and water soluble calcium. There were significant positive correlationship between total calcium and exchange calcium, and between exchange calcium and water soluble calcium. It was shown that terrain affected not only the horizontal but also the vertical distribution of soil calcium.